THE POLYMER SOCIETY OF KOREA

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세션명 대학원생 구두발표 (II)
발표장 제11-1회장
논문코드 O11-3
발표일 2024-04-3
발표시간 13:30-13:45
논문제목 Organic solvent dispersible MXene for band alignment and interface engineering of colloidal quantum dot photovoltaics
발표자 유형렬
발표자 소속 DGIST
저자 유형렬, 최종민
소속 DGIST
논문초록 Despite the recent developments in colloidal quantum dot (CQD) photovoltaics the unfavorable energy band for hole collection and the surface cracks lowers the device performance. To address these issues, we developed polycatechol functionalized MXene (PCA-MXene), which act as an interlayer and a dopant and an interlayer in CQD photovoltaics. PCA-MXene achieves a consistently dispersed mixture in a butylamine solvent, which makes MXene and CQDs work together effectively. As a result, the energy band alignment is modulated and the work function of CQDs is altered, which eventually leads to improved hole extraction. Furthermore, the surface cracks in the thiol-treated CQD layer eliminated by the PCA-MXene interlayer. Owing to these benefits, the PCA-MXene-integrated CQD device shows a 13.6% power conversion efficiency (PCE) compared to the reference device, which has a PCE of 12.8%.